CH₄+2O₂-to>CO₂+2H₂O

x------2x---------x

C₂H₄+3O₂-to>2CO₂+2H₂O

y----------3y--------2y

=>\(\left\{{}\begin{matrix}x+y=\dfrac{5,6}{22,4}\\2x+3y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,15 mol , y=0,1 mol

=>%V_CH4=\(\dfrac{0,15.22,4}{5,6}\).100=60%

=>%V_C2H4=100-60=40%

b)

V_CO2=(0,15+0,1.2).22,4=7,84l

mhh khí = 5,6/22,4 = 0,25 (mol)

nO2 = 13,44/22,4 = 0,6 (mol)

Gọi nC2H4 = a (mol); nCH4 = b (mol)

a + b = 0,25 (1)

PTHH:

C2H4 + 3O2 -> (t°) 2CO2 + 2H2O

Mol: a ---> 3a ---> 2a

CH4 + 2O2 -> (t°) CO2 + 2H2O

Mol: b ---> 2b ---> b

3a + 2b = 0,6 (2)

(1)(2) => a = 0,1 (mol); b = 0,15 (mol)

%VC2H4 = 0,1/0,25 = 40%

%VCH4 = 100% - 40% = 60%

VCO2 = (0,1 . 2 + 0,15) . 22,4 = 7,84 (l)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH:

2CO + O₂ --t^o--> 2CO₂

0,2<---0,1<--------0,2

2H₂ + O₂ --t^o--> 2H₂O

0,4<--0,2<-------0,2

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\\%V_{H_2}=100\%-33,33\%=66,67\%\end{matrix}\right.\)

\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: 2CO + O₂ --t^o--> 2CO₂

            0,3<--0,15<------0,3

            2H₂ + O₂ --t^o--> 2H₂O

            0,1<--0,05

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\%n_{CO}=\dfrac{0,3}{0,3+0,1}.100\%=75\%\\\%V_{H_2}=100\%-75\%=25\%\end{matrix}\right.\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\left(1\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{56}{22,4}=2,5\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,5\left(mol\right)\\n_{C_2H_2}=1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,5.22,4}{33,6}.100\%\approx33,33\%\\\%V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)

b, Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=3,5\left(mol\right)\Rightarrow m_{O_2}=3,5.32=112\left(g\right)\)

Đáp án A

Crackinh butan → 1 mol hhX.

X đi qua brom dư thì còn 13,44 lít hhY. Đốt cháy 0,6 lít hhY → 1,3 lít CO₂.

• Đốt cháy 0,6 lít hhY gồm các ankan thu được 1,3 lít CO₂

→ Đốt cháy 13,44 lít hhY thì thu được:  

Vì hhY gồm ankan

→ V_H2O = V_CO2 + V_ankan = 13,44 + 29,12 = 42,56 lít.

Theo BTNT O: V_O2 = (2 x V_CO2 + V_H2O) : 2

= (29,12 x 2 + 42,56) : 2 = 50,4 lít

a)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\)

PTHH: 2H₂ + O₂ --t^o--> 2H₂O

            0,1<-0,05<-------0,1

            2CO + O₂ --t^o--> 2CO₂

            0,2<--0,1-------->0,2

=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\V_{CO}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)

b) \(m_{CO_2}=0,2.44=8,8\left(g\right)\)

\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(n_{H_2O}=\dfrac{1,8}{18}=0,1mol\)

\(2CO+O_2\rightarrow2CO_2\)

  a         0,5a     a

\(2H_2+O_2\rightarrow2H_2O\)

 0,1   0,05 \(\leftarrow\)    0,1

\(\Sigma n_{O_2}=0,5a+0,05=0,15\)

\(\Rightarrow a=n_{O_2\left(CO\right)}=0,2mol\)

\(V_{CO}=2\cdot0,2\cdot22,4=8,96l\)

\(V_{H_2}=0,1\cdot22,4=2,24l\)

\(m_{CO_2}=0,2\cdot44=8,8g\)

nO2(tổng)=0,3(mol); nCO2=0,2(mol)

CO + 1/2 O2 -to-> CO2 (1)

0,2<----0,1<-------0,2(mol)

H2 + 1/2 O2 -to-> H2O (2)

0,4<---0,2<-------0,4(mol)

nO2(2)= nO2(tổng)- nO2(1)=0,3-0,1=0,2(mol)

Vì số mol tỉ lệ thuận thể tích:

=> %V(CO/hh)= [0,2/(0.2+0,4)].100=33,333%

=>%V(H2/hh)=100%-33,333%=66,667%

a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)

\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)

\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)

b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)

\(\rightarrow V_{kk}=4,48.5=11,2l\)

c. Có \(n_{Mg}=2n_{O_2}=0,2l\)

\(\rightarrow m_{Mg}=0,2.24=4,8g\)

\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)

\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)

a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(1\right)\)

\(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,25\left(mol\right)\\n_{C_2H_2}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,25.22,4}{6,72}.100\%\approx83,33\%\\\%V_{C_2H_2}\approx16,67\%\end{matrix}\right.\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,625\left(mol\right)\Rightarrow m_{O_2}=0,625.32=20\left(g\right)\)